* President Luis Echeverría
*
* (1975 - 1976) : Julio Hirschfeld Almada
* President José López Portillo
*
* (1976 - 1980) : Guillermo Rossell de la Lama
*
* (1980 - 1982) : Rosa Luz Alegría Escamilla
* President Miguel de la Madrid
*
* (1982 - 1988) : Antonio Enríquez Savignac
* President Carlos Salinas de Gortari
*
* (1988 - 1990) : Carlos Hank González
*
* (1990 - 1993) : Pedro Joaquín Coldwell
*
* (1993 - 1994) : Jesús Silva Herzog Flores
* President Ernesto Zedillo
*
* (1994 - 1997) : Silvia Hernández Enríquez
*
* (1997 - 2000) : Óscar Espinosa Villarreal
* President Vicente Fox
*
* (2000 - 2004) : Leticia Navarro
*
* (2004 - 2006) : Rodolfo Elizondo Torres
* President Felipe Calderón
*
* (2006 - 2010) : Rodolfo Elizondo Torres
*
* (2010 - 2012) : Gloria Guevara Manzo
* President Enrique Peña Nieto
*
* (2012 - 2015) : Claudia Ruiz Massieu
*
* (2015 - present) : Enrique de la Madrid Cordero